Intro To Fossil Fuels

Feb 2019

Formed over millions of years, it’s amazing that fossils fuels exist. They have increased our standard of living more than anything else and made the world the way it is today. Today, 87% of the world’s primary energy is from fossil fuels. In this article I will give an overview of these fuel sources.

Coal, Crude Oil and Natural Gas

Coal

Millions of years ago, plants died and other plants died on these plants forming peat. With every additional layer of plant matter, the layers below were compressed and heated forming coal, a carbon rich and energy density material.

Coal was the critical fuel of the Industrial Revolution - vital for steam engines and furnaces. Transitioning from wood to coal because it was cheaper and more energy dense

Not all coal is the same, the two most important factors to classifying coal are its calorific value (how much energy can it release when burned) and its percent of carbon (other atoms are hydrogen, sulfur, oxygen and nitrogen are common).

Type Produced
Bituminous 46%
Subbituminous 45%
Lignite 9%
Anthracite <1%

Coal can also be used to form coke, which improves its carbon purity. With the increased purity, it can be burned at higher temperatures, important as a fuel and reducing agent in smelting iron ore.

Coal main use is the generation of electricity, boiling water into steam and spins a turbine and generator to create electricity. This has a thermodynamic efficiency between 25% to 50%.

With newer technologies, the coal can be convert the coal to Syngas to a heat recovery steam generator. This powers a steam turbine and the waste heat can be used to heat another process or a building. This power plant could reach efficiencies up to 94%.

Stats

We can divide the end use into direct, either in a vehicle or in a manufacturing process and electricity where we make electricity first. Out of the three fossil fuels coal is the most difficult to transport and creates the most pollution. Therefore is popular in electricity generation outside of cities.

Direct 32%

Cost 3.9 USD/GJ
Specific Energy 0.030 GJ/kg
Energy Density 38 GJ/m^3
Emission Intensity 96 kgCO2e/GJ

Electricity Generation 68%

Cost 34.7 USD/GJ
Emission Intensity 265 kgCO2e/GJ

Crude Oil

Also known as Petroleum

Formed when zooplankton and algae died and buried underneath sedimentary rock and compressed and heated for millions of years. Crude oil is a combination of many different carbon chains. These carbon chains are separated using a process called fractional distillation, by each chain’s boiling point. These form products such as gasoline, diesel, methane, asphalt and chemicals to make plastic.

As the same with coal, not all crude oil is the same. Coal is usually classified to where it is found, for example “WTI”, “Bret” and “Oman”. These large pockets all have similar characteristics and the fuel from these sources have similar characteristics.

When comparing these pockets, the two largest factors are its sulfur content and API gravity. API gravity is a function of density and is a measure on how heavy or light the crude oil is.

A high API is desired as more gasoline can be extracted from it and a low sulfur content is desired as less processing is needed to remove or capture the excess sulfur.

Stats

Most crude oil is refined into fuels that we use in a vehicle, gasoline, diesel and jet fuel. Very little is used in electrical generation, therefore I was not able to find a cost of generating electricity. For direct use, I am showing gasoline.

Direct 96%

Cost 14.0 USD/GJ
Specific Energy 0.046 GJ/kg
Energy Density 34 GJ/m^3
Emission Intensity 70 kgCO2e/GJ

Electricity Generation 4%

Natural Gas


Natural gas consists of mostly methane. Similar to crude oil and coal it is formed from decaying organic matter and therefore is found close to both coal and crude oil layers. When extracting oil in the 19th and 20th century it was common to burn off the unwanted natural gas.

Natural gas is very important and is mostly used directly. It is a low density fuel compared to crude oil and coal, so it has limitation were it can be used. But, it is relatively clean burning, making it useful domestic heating and electricity generation.

Natural gas is classified by how pure the methane is but is not a large a factor as seen in crude oil and coal. Processing the natural gas involves striping out sulfur, ethane, propane, butanes and natural gasoline so it is under limits.

When converting to electricity, most natural gas-fire electrical generation uses a combined-cycle gas turbines process with a conversion efficiency of 62%.

Stats

Natural gas is used both in direct consumption for heating, cooking and in electrical generation. It also has lower CO2 emissions than other fossil fuels making it more environmentally friendlily option in comparison.

Direct 58%

Cost 3.35 USD/GJ
Specific Energy 0.056 GJ/kg
Energy Density 22 GJ/m^3
Emission Intensity 56 kgCO2e/GJ

Electricity Generation 42%

Cost 27.46 USD/GJ
Emission Intensity 166 kgCO2e/GJ

I hope this was a useful introduction to the largest energy sources that we use. I always heard about renewable energy but feel like I didn’t understand the energy system until I studied fossil fuels. They all have their benefits and drawbacks but I believe they will be important in the future.

In this write up I made a lot of assumptions and each number depends on my factors. Take these numbers with a grain of salt.

Thank you for reading.

References